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Synthesis and catalytic activity of nanoporous aluminosilicate materials

Robinson, M. W. C., Davies, A. M., Mabbett, I., Apperley, D. C., Taylor, Stuart Hamilton and Graham, Andrew E. 2009. Synthesis and catalytic activity of nanoporous aluminosilicate materials. Journal of Molecular Catalysis A: Chemical 314 (1-2) , pp. 10-14. 10.1016/j.molcata.2009.09.005

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Abstract

A range of nanoporous aluminosilicates varying in their aluminium content were synthesised using an evaporation-induced self-assembly (EISA) approach under acidic conditions. The nanoporous materials produced display narrow pore size distributions and the expected large BET surface areas. The activity and selectivity of these materials to function as Lewis acid catalysts for the addition of alcohols to styrene oxide and cyclohexene oxide were assessed and found to be optimum using high aluminium containing materials. © 2009 Elsevier B.V. All rights reserved.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Neuroscience and Mental Health Research Institute (NMHRI)
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: Acidic conditions; Aluminium content; Aluminosilicate materials; BET surface area; Catalytic activity; Cyclohexene oxide; Evaporation-induced self-assembly; Lewis acid catalysts; Nano-porous; Nanoporous Materials; Narrow pores; Styrene oxide, Acids; Aluminosilicates; Aluminum; Catalysis; Evaporation; Olefins; Pore size; Self assembly; Styrene; Vapors, Catalyst selectivity
Additional Information: cited By (since 1996) 4
Publisher: Elsevier BV
ISSN: 13811169
Last Modified: 04 Jun 2017 02:10
URI: http://orca.cf.ac.uk/id/eprint/10249

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