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Possible role for Cu(II) compounds in the oxidation of malonyl dichloride and HCl at Cu(110) surfaces

Davies, Philip Rosser, Edwards, Dyfan and Richards, Darran 2009. Possible role for Cu(II) compounds in the oxidation of malonyl dichloride and HCl at Cu(110) surfaces. Journal of Physical Chemistry. C 113 (24) , pp. 10333-10336. 10.1021/jp903042f

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Abstract

The pathway for the chlorination of Cu(110) surfaces by malonyl dichloride and HCl is changed in the presence of oxygen with STM results suggesting the formation of a surface CuCl2 state at room temperature that may have implications for mechanistic models of the Deacon process and of dioxin formation at aerosol particle surfaces.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Subjects: Q Science > QD Chemistry
Publisher: American Chemical Society
ISSN: 1932-7447
Last Modified: 20 Oct 2017 16:13
URI: http://orca.cf.ac.uk/id/eprint/10334

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