Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Asymmetric hetero-Diels-Alder reactions. Mechanism of the reaction of alkenyloxazolines with isocyanates

Elliott, Mark Christopher, Kruiswijk, Elbertus and Willock, David James 1998. Asymmetric hetero-Diels-Alder reactions. Mechanism of the reaction of alkenyloxazolines with isocyanates. Tetrahedron Letters 39 (48) , pp. 8911-8914. 10.1016/S0040-4039(98)01949-2

Full text not available from this repository.

Abstract

Diastereomerically pure oxazolo[3,2-c]pyrimidines can be readily prepared by the reaction of alkenyloxazolines with isocyanates. These compounds undergo epimerisation upon prolonged heating. The mechanism of this transformation has been investigated experimentally and computationally. Diastereomerically pure oxazolo[3,2-c]pyrimidines can be prepared by hetero-Diels-Alder reaction of alkenyloxazolines. The mechanism of the formation and isomerisation of these compounds is discussed.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: Asymmetric synthesis; Diels-Alder reaction
Publisher: Elsevier
ISSN: 0040-4039
Funders: Cardiff University, The Royal Society, The Nuffield Foundation, Pfizer Central Research, EPSRC, ICI Katalco, OCF
Last Modified: 03 Nov 2017 01:40
URI: http://orca.cf.ac.uk/id/eprint/10373

Citation Data

Cited 16 times in Google Scholar. View in Google Scholar

Cited 15 times in Scopus. View in Scopus. Powered By Scopus® Data

Cited 15 times in Web of Science. View in Web of Science.

Actions (repository staff only)

Edit Item Edit Item