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How to synthesise high purity, crystalline D-glucaric acid selectively

Armstrong, Robert, Kariuki, Benson, Knight, David and Hutchings, Graham John 2017. How to synthesise high purity, crystalline D-glucaric acid selectively. European Journal of Organic Chemistry 2017 (45) , pp. 6811-6814. 10.1002/ejoc.201701343

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Abstract

Glucaric acid has potential applications in food, pharmaceutical and polymer industries yet no methodology exists within the public domain for isolation of this key bio-derived platform molecule as a pure, crystalline solid. Here we demonstrate the difficulties, which arise in doing so and report development of a process for derivation of free-glucaric acid from its Ca2+/K+ glucarate salts, which are both commercially available. Employing Amberlyst-15 (H+) exchange resin and azeotrope drying, powdered glucaric acid is prepared at > 99.96 % purity in 98.7 % dry yield.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Cardiff Catalysis Institute (CCI)
Chemistry
Publisher: Wiley
ISSN: 1434-193X
Funders: EPSRC
Date of First Compliant Deposit: 7 December 2017
Date of Acceptance: 31 October 2017
Last Modified: 28 Feb 2018 11:12
URI: http://orca.cf.ac.uk/id/eprint/107395

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