Exploring tandem ruthenium-catalyzed hydrogen transfer and SNAr chemistry

Polidano, Kurt, Reed-Berendt, Benjamin, Basset, Anais, Watson, Andrew, Williams, Jonathan M. J. and Morrill, Louis 2017. Exploring tandem ruthenium-catalyzed hydrogen transfer and SNAr chemistry. Organic Letters 19 (24) , pp. 6716-6719. 10.1021/acs.orglett.7b03441

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Abstract

A hydrogen-transfer strategy for the catalytic functionalization of benzylic alcohols via electronic arene activation, accessing a diverse range of bespoke diaryl ethers and aryl amines in excellent isolated yields (38 examples, 70% average yield), is reported. Taking advantage of the hydrogen-transfer approach, the oxidation level of the functionalized products can be selected by judicious choice of simple and inexpensive additives.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Chemistry
Publisher:	ACS
ISSN:	1523-7060
Funders:	Engineering and Physical Sciences Research Council
Date of First Compliant Deposit:	23 January 2018
Date of Acceptance:	6 December 2017
Last Modified:	27 Jan 2020 10:00
URI:	http://orca.cf.ac.uk/id/eprint/108362

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