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Designing Pd-based supported bimetallic catalysts for environmental applications

Nowicka, Ewa and Meenakshisundaram, Sankar 2018. Designing Pd-based supported bimetallic catalysts for environmental applications. Journal of Zhejiang University-SCIENCE A 19 (1) , pp. 5-20. 10.1631/jzus.A1700257

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Abstract

Supported bimetallic nanoparticulate catalysts are an important class of heterogeneous catalysts for many reactions including selective oxidation, hydrogenation/hydrogenolysis, reforming, biomass conversion reactions, and many more. The activity, selectivity, and stability of these catalysts depend on their structural features including particle size, composition, and morphology. In this review, we present important structural features relevant to supported bimetallic catalysts focusing on Pd-based bimetallic systems and recently reported strategies to control them through different synthesis methodologies. Further, we focus on a few reactions that are relevant to environmental catalysis, i.e. CO oxidation, hydrocarbon oxidation, hydrodechlorination, and NO x decomposition, where Pd-based catalysts are often used successfully. In spite of much progress in these areas, still there is a need for more advanced catalytic technologies to address the grand challenges like environmental remediation. Some of the recent advances in the design of bimetallic catalysts were made because of the combined efforts of material scientists, spectroscopists, microscopists, catalysis chemists, and engineers through state-of-the-art characterization methodologies, mechanistic investigations, and structure-activity correlations. This review is aimed at inspiring scientists to rationally design catalysts for a green and sustainable future.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Cardiff Catalysis Institute (CCI)
Chemistry
Publisher: Springer Verlag
ISSN: 1673-565X
Date of First Compliant Deposit: 7 February 2018
Date of Acceptance: 28 November 2017
Last Modified: 28 Jun 2019 20:10
URI: http://orca.cf.ac.uk/id/eprint/108939

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