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Total synthesis of carbocyclic nikkomycin C

Ward, Simon, Holmes, Andrew B. and McCague, Ray 1997. Total synthesis of carbocyclic nikkomycin C. Chemical Communications- Royal Society of Chemistry (21) , pp. 2085-2086. 10.1039/a705825j

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Abstract

The carbocyclic analogue 11 of nikkomycin C 1 is prepared by a sequence involving allylic rearrangement of the imino ester adduct 3, palladium-mediated substitution of the allylic lactone 4c with uracil bis(trimethylsilyl)ether 6, and osmylation of the double bond.

Item Type: Article
Status: Published
Schools: Medicine
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Last Modified: 23 Feb 2018 14:47
URI: http://orca.cf.ac.uk/id/eprint/109419

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