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Alternative strategies with iodine: Fast access to new iodine(III) compounds

Hokamp, Tobias, Mollari, Leonardo, Wilkins, Lewis C., Melen, Rebecca L. and Wirth, Thomas 2018. Alternative strategies with iodine: Fast access to new iodine(III) compounds. Angewandte Chemie International Edition 57 (27) , pp. 8306-8309. 10.1002/anie.201804642
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Non‐iodinated arenes are easily and selectively converted into (diacetoxyiodo)arenes in a single step under mild conditions using iodine triacetates as reagents. The oxidative step is decoupled from the synthesis of hypervalent iodine(III) reagents which can now be prepared conveniently in a one‐pot synthesis for subsequent reactions without prior purification. The chemistry of iodine triacetates was also expanded to heteroatom ligand exchanges to form novel inorganic hypervalent iodine compounds.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Wiley-VCH Verlag
ISSN: 1433-7851
Date of First Compliant Deposit: 15 May 2018
Date of Acceptance: 9 May 2018
Last Modified: 19 Jul 2018 13:27

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