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Structural evolution in metallomicroemulsions – the effect of increasing alcohol hydrophobicity

Paul, Alison, Fallis, Ian A., Stokes, Emily, King, Stephen M. and Griffiths, Peter C. 2018. Structural evolution in metallomicroemulsions – the effect of increasing alcohol hydrophobicity. Dalton Transactions 47 (40) , pp. 14211-14217. 10.1039/C8DT02031K

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Abstract

Small-angle neutron scattering and contrast variation has been employed to quantify how a series of alcohols with increasing hydrophobicity exert different abilities to structure a model toluene based metallomicroemulsion – a microemulsion system stabilised with a metallosurfactant. Classical microemulsion phase evolution and droplet structure are observed, leading to an oil rich core stabilised by a surfactant film containing a highly concentrated, hydrated metal ion layer.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1477-9226
Date of First Compliant Deposit: 15 August 2018
Date of Acceptance: 25 July 2018
Last Modified: 19 Oct 2019 03:57
URI: http://orca.cf.ac.uk/id/eprint/114194

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