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Arsenic catalysis: Hydroboration of aldehydes using a benzo-fused diaza-benzyloxy-arsole

Melen, Rebecca and Ould, Darren 2018. Arsenic catalysis: Hydroboration of aldehydes using a benzo-fused diaza-benzyloxy-arsole. Chemistry - A European Journal 10.1002/chem.201803508

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Abstract

The first example of a homogenous As(III) catalyst for hydroboration has been established. The reaction of N,N'‐diisopropylbenzene diamine or toluene‐3,4‐dithiol with AsCl3 yielded the chloroarsoles (1 and 2) which upon reaction with benzyl alcohol led to the the benzyloxy benzo‐1,3,2‐diazaarsole (3) and benzo‐1,3,2‐dithiaarsole (4) respectively. 3 was found to be an excellent catalyst for the hydroboration of aldehyde substrates.

Item Type: Article
Date Type: Published Online
Status: Published
Schools: Chemistry
Publisher: Wiley: 12 months
ISSN: 0947-6539
Date of First Compliant Deposit: 5 September 2018
Date of Acceptance: 8 August 2018
Last Modified: 08 Aug 2019 02:05
URI: http://orca.cf.ac.uk/id/eprint/114651

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