Bahili, Mohammed A., Stokes, Emily C., Amesbury, Robert C., Ould, Darren M. C., Christo, Bashar, Horne, Rhian, Kariuki, Benson M., Stewart, Jack A., Taylor, Rebekah L., Williams, Andrew, Jones, Matthew D., Harris, Kenneth D. M. and Ward, Benjamin D.
2019.
Aluminium-catalysed isocyanate trimerization, enhanced by exploiting a dynamic coordination sphere.
Chemical Communications
55
(53)
, pp. 7679-7682.
10.1039/C9CC03339D
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Official URL: http://dx.doi.org/10.1039/C9CC03339D
Abstract
Main-group metals are inherently labile, hindering their use in catalysis. We exploit this lability in the synthesis of isocyanurates. For the first time we report a highly active catalyst that trimerizes alkyl, allyl and aryl isocyanates, and di-isocyanates, with low catalyst loadings under mild conditions, using a hemi-labile aluminium-pyridyl-bis(iminophenolate) complex.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Publisher: | Royal Society of Chemistry |
ISSN: | 1359-7345 |
Funders: | EPSRC |
Date of First Compliant Deposit: | 18 June 2019 |
Date of Acceptance: | 14 May 2019 |
Last Modified: | 11 Dec 2020 03:01 |
URI: | http://orca.cf.ac.uk/id/eprint/123542 |
Citation Data
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