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The direct synthesis of hydrogen peroxide over Au-Pd supported nanoparticles under ambient conditions

Santos Hernandez, Alba, Lewis, Richard James, Malta, Grazia, Howe, Alexander, Morgan, David John, Hampton, Euan, Gaskin, Paul and Hutchings, Graham J. 2019. The direct synthesis of hydrogen peroxide over Au-Pd supported nanoparticles under ambient conditions. Industrial & Engineering Chemistry Research 58 (28) , pp. 12623-12631. 10.1021/acs.iecr.9b02211

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Abstract

The direct synthesis of hydrogen peroxide (H2O2) from molecular H2 and O2 over Au-Pd / TiO2 catalysts prepared using a modified impregnation methodology is studied. Initially we investigated the role of Au: Pd ratio on the catalytic activity towards H2O2 formation and its subsequent degradation under conditions that have previously been found to be optimal for the formation of H2O2 using high pressure reactants and low temperatures. Subsequently, we have conducted a detailed study of H2O2 synthesis under ambient conditions which are both more challenging for achieving high yields of H2O2 and are more likely to be used for future industrial applications.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Publisher: American Chemical Society
ISSN: 0888-5885
Funders: Dwr Cymru Welsh Water
Date of First Compliant Deposit: 1 July 2019
Date of Acceptance: 25 June 2019
Last Modified: 29 Jun 2020 13:46
URI: http://orca.cf.ac.uk/id/eprint/123851

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