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Preparation and catalytic properties of resin bound binuclear rhodium tetracarboxylate complexes

Andersen, Jo-Ann M., Karodia, Nazira, Miller, David James, Stones, Duane and Gani, David 1998. Preparation and catalytic properties of resin bound binuclear rhodium tetracarboxylate complexes. Tetrahedron Letters 39 (42) , pp. 7815-7818. 10.1016/S0040-4039(98)01709-2

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Abstract

-(4′-Polystyrylmethyloxy)-3-carboxylatomethyloxy-1-phenylacetate bis-μ-coordinated rhodium(II) diacetate complex, a resin-bound analogue of dirhodium tetraacetate in which two adjacent μ-bridging acetate moieties are covalently linked, serves as an efficient, stable and re-useable immobilised alkene hydrofomylation and hydrogenation catalyst. 4-(4′-Polystyrylmethyloxy)-3-carboxylatomethyloxy-1-phenylacetate bis-μ-coordinated rhodium(II) diacetate complex (3) serves as a polymer-supported catalyst for alkene hydroformylation and hydrogenation

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Elsevier
ISSN: 0040-4039
Last Modified: 04 Jun 2017 02:49
URI: http://orca.cf.ac.uk/id/eprint/12507

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