Synthesis, characterisation and theoretical studies of amidinato-indium(I) and thallium(I) complexes: isomers of neutral group 13 metal(I) carbene analogues

Jones, Cameron James, Junk, Peter C., Platts, James Alexis ORCID: https://orcid.org/0000-0002-1008-6595, Rathmann, Daniel and Stasch, Andreas ORCID: https://orcid.org/0000-0002-7407-8287 2005. Synthesis, characterisation and theoretical studies of amidinato-indium(I) and thallium(I) complexes: isomers of neutral group 13 metal(I) carbene analogues. Dalton Transactions (15) , pp. 2497-2499. 10.1039/B507242E

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Abstract

The synthesis and characterisation of the monomeric amidinato-indium(I) and thallium(I) complexes, [M(Piso)]·PisoH, M = In or Tl, Piso− = [ArNC(But)NAr]−, Ar = C6H3Pri2-2,6, are reported. These complexes, in which the metal centre is chelated by the amidinate ligand in an N,η3-arene-fashion, can be considered as isomers of four-membered group 13 metal(I) carbene analogues. Theoretical studies have compared the relative energies of both isomeric forms of a model complex, [In{PhNC(H)NPh}].

Item Type:	Article
Status:	Published
Schools:	Chemistry
Subjects:	Q Science > QD Chemistry
Publisher:	Royal Society of Chemistry
ISSN:	0300-9246
Last Modified:	18 Oct 2022 13:09
URI:	https://orca.cardiff.ac.uk/id/eprint/12526

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