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Synthesis, characterisation and theoretical studies of amidinato-indium(I) and thallium(I) complexes: isomers of neutral group 13 metal(I) carbene analogues

Jones, Cameron James, Junk, Peter C., Platts, James Alexis, Rathmann, Daniel and Stasch, Andreas 2005. Synthesis, characterisation and theoretical studies of amidinato-indium(I) and thallium(I) complexes: isomers of neutral group 13 metal(I) carbene analogues. Dalton Transactions (15) , pp. 2497-2499. 10.1039/B507242E

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Abstract

The synthesis and characterisation of the monomeric amidinato-indium(I) and thallium(I) complexes, [M(Piso)]·PisoH, M = In or Tl, Piso− = [ArNC(But)NAr]−, Ar = C6H3Pri2-2,6, are reported. These complexes, in which the metal centre is chelated by the amidinate ligand in an N,η3-arene-fashion, can be considered as isomers of four-membered group 13 metal(I) carbene analogues. Theoretical studies have compared the relative energies of both isomeric forms of a model complex, [In{PhNC(H)NPh}].

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 0300-9246
Last Modified: 19 Dec 2017 03:04
URI: http://orca.cf.ac.uk/id/eprint/12526

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