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1,1,2-Trimethylpropyldialkylcyanoborates as intermediates for the synthesis of symmetrical, unsymmetrical, functionalised, and cyclic ketones

Pelter, Andrew, Hutchings, M. G. and Smith, Keith 1971. 1,1,2-Trimethylpropyldialkylcyanoborates as intermediates for the synthesis of symmetrical, unsymmetrical, functionalised, and cyclic ketones. Journal of the Chemical Society. D, Chemical communications (18) , pp. 1048-1050. 10.1039/C29710001048

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Abstract

The insertion reaction of cyanide into hexyldialkylcyanoborates, using acylation at low temperatures followed by oxidation, provides the mildest known method for the high-yield production of ketones from olefins i in organoboranes.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 0009-241x
Last Modified: 04 Jun 2017 02:50
URI: http://orca.cf.ac.uk/id/eprint/12573

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