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The chemistry of organoborates. Part 3. Protonation of trialkylcyanoborates

Pelter, Andrew, Hutchings, Michael G. and Smith, Keith 1975. The chemistry of organoborates. Part 3. Protonation of trialkylcyanoborates. Journal of the Chemical Society, Perkin Transactions 1 (2) , pp. 142-145. 10.1039/P19750000142

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Abstract

Protonation of trialkylcyanoborates in bis-(2-methoxyethyl) ether (diglyme) leads to migration of two alkyl groups from boron to carbon and the production of derivatives of 1,4-diaza-2,5-diboracyclohexane. On oxidation, these compounds yield ketones.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 0300-922X
Last Modified: 04 Jun 2017 02:50
URI: http://orca.cf.ac.uk/id/eprint/12581

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