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The chemistry of organoborates. Part 2. High yield syntheses of trialkylmethanols by the cyanoborate process

Pelter, A., Hutchings, Michael G., Rowe, Keith and Smith, Keith 1975. The chemistry of organoborates. Part 2. High yield syntheses of trialkylmethanols by the cyanoborate process. Journal of the Chemical Society, Perkin Transactions 1 (2) , pp. 138-142. 10.1039/P19750000138

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Abstract

Treatment of trialkylcyanoborates with an excess of trifluoroacetic anhydride induces three migrations from boron to carbon and conditions are defined for the migration of alkyl groups of differing bulk. Oxidative work-up of the reactions gives trialkymethanols in good yield.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 0300-922X
Last Modified: 04 Jun 2017 02:50
URI: http://orca.cf.ac.uk/id/eprint/12582

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