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Reaction of higher dialkyl(methylthio)boranes with bromine: a new synthesis of dialkylbromoboranes

Pelter, Andrew, Rowe, Keith, Sharrocks, David N., Smith, Keith and Subrahmanyam, Chitti 1976. Reaction of higher dialkyl(methylthio)boranes with bromine: a new synthesis of dialkylbromoboranes. Journal of the Chemical Society. Dalton Transactions (20) , pp. 2087-2090. 10.1039/DT9760002087

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Abstract

Higher dialkyl(methylthio)boranes, readily prepared in situ from the corresponding trialkylboranes, react rapidly at low temperature with bromine to give dialkylbromoboranes and dimethyl disulphide. Removal of the latter under reduced pressure gives a pure product in excellent yield.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 0300-9246
Last Modified: 04 Jun 2017 02:50
URI: http://orca.cf.ac.uk/id/eprint/12609

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