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Synthesis of secondary or tertiary alcohols by reactions of trialkylboranes with acyl carbanion equivalents

Hughes, Rosemary J., Ncube, Smollie, Pelter, Andrew, Smith, Keith, Negishi, Ei-ichi and Yoshida, Takao 1977. Synthesis of secondary or tertiary alcohols by reactions of trialkylboranes with acyl carbanion equivalents. Journal of the Chemical Society, Perkin Transactions 1 (10) , pp. 1172-1176. 10.1039/P19770001172

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Abstract

Reactions of trialkylboranes (R23B) with 1-lithio-1,1-bis(phenylthio)alkanes [R1(PhS)2C–Li+; R1= H or Prn], followed by reaction with mercury(II) chloride and oxidative work-up, give high yields of secondary (R1= H) or tertiary (R1= Prn) alcohols (R1R22COH).

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 0300-922X
Last Modified: 04 Jun 2017 02:50
URI: http://orca.cf.ac.uk/id/eprint/12613

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