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Preparation of trans,trans,trans- and cis,cis,trans-perhydrophenalen-9-ols by application of the three-migration cyanoborate process to isomeric perhydro-9b-boraphenalenes: differences between the cyanoborate and carbonylation reactions

Pelter, Andrew, Maddocks, Peter J. and Smith, Keith 1978. Preparation of trans,trans,trans- and cis,cis,trans-perhydrophenalen-9-ols by application of the three-migration cyanoborate process to isomeric perhydro-9b-boraphenalenes: differences between the cyanoborate and carbonylation reactions. Journal of the Chemical Society. Chemical communications (18) , pp. 805-806. 10.1039/C39780000805

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Abstract

Application of the three-migration cyanoborate process to cis,cis-perhydro-9b-boraphenalene gives trans,trans,trans-perhydrophenalen-9-ol, in contrast to carbonylation which gives the cis,cis,cis-isomer; cis-trans-perhydro-9b-boraphenalene gives cis,cis,trans-perhydro-phenalen-9-ol by either process.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 0022-4936
Last Modified: 04 Jun 2017 02:50
URI: http://orca.cf.ac.uk/id/eprint/12627

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