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Reaction of di-n-hexylbromoborane with di-isopropylcarbamoyl-lithium: X-ray crystal structure of 2,2,5,5-tetra-n-hexyl-4,6-bis(di-isopropyliminio)-2,5-diborata-1,3-dioxacyclohexane, a new organoborane which is remarkably resistant to oxidation

Fletcher, Andrew S., Paget, Walter E., Smith, Keith, Swaminathan, Kalyanaraman and Haley, Martin J. 1979. Reaction of di-n-hexylbromoborane with di-isopropylcarbamoyl-lithium: X-ray crystal structure of 2,2,5,5-tetra-n-hexyl-4,6-bis(di-isopropyliminio)-2,5-diborata-1,3-dioxacyclohexane, a new organoborane which is remarkably resistant to oxidation. Journal of the Chemical Society. Chemical communications (13) , pp. 573-574. 10.1039/C39790000573

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Abstract

5-Di-isopropyliminio-2,2,4,4-tetra-n-hexyl-2,4-diborata-1-oxa-3-oxoniacyclopentane (1, R = n-hexyl) and 2,2,5,5-tetra-n-hexyl-4,6-bis(di-isopropyliminio)-2,5-diborata-1,3-dioxacyclohexane (2) have been obtained from reactions of di-n-hexylbromoborane with di-iso-propylcarbamoyl-lithium; compound (2) is the first example of a new class of organoboranes and is remarkably resistant to oxidation, being unaffected by 50% hydrogen peroxide and base.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 0022-4936
Last Modified: 04 Jun 2017 02:50
URI: http://orca.cf.ac.uk/id/eprint/12637

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