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Synthesis and chemiluminescent evaluation of a series of phenyl N-alkylacridinium 9-carboxylates

Batmanghelich, Shariar, Woodhead, J. Stuart, Smith, Keith and Weeks, Ian 1991. Synthesis and chemiluminescent evaluation of a series of phenyl N-alkylacridinium 9-carboxylates. Journal of Photochemistry and Photobiology A: Chemistry 56 (2-3) , pp. 249-254. 10.1016/1010-6030(91)80025-D

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Abstract

The nitrogen atom of phenyl acridine-9-carboxylate was alkylated with several alkylating agents using thermal, photochemical and sonochemical techniques. Thermal reactions were only suitable for methylation and ethylation, but irradiation with UV light for ultrasound allowed the synthesis of n-propyl iso-propyl and benzyl derivatives. Use of ultrasound produced cleaner product mixtures than UV irradiation. The quantum yields and kinetics of the chemiluminescent reactions of the products with alkaline hydrogen peroxide were found to be independent of the nature of the N-alkyl group.

Item Type: Article
Status: Published
Schools: Chemistry
Medicine
Systems Immunity Research Institute (SIURI)
Subjects: Q Science > QD Chemistry
Publisher: Elsevier
ISSN: 1010-6030
Last Modified: 04 Jun 2017 02:50
URI: http://orca.cf.ac.uk/id/eprint/12654

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