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Synthesis of 1-arylalk-2-enes and 1-arylalkanes via Friedel–Crafts alkylation with allylic alcohols catalysed by an acidic clay

Smith, Keith and Pollaud, Guy M. 1994. Synthesis of 1-arylalk-2-enes and 1-arylalkanes via Friedel–Crafts alkylation with allylic alcohols catalysed by an acidic clay. Journal of the Chemical Society, Perkin Transactions 1 (24) , pp. 3519-3520. 10.1039/P19940003519

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Abstract

Moderately activated benzenoid compounds undergo alkylation with allylic alcohols in the presence of acidic K10 clay to give almost exclusively 1-arylalk-2-enes by attack at the terminal position of the intermediate allyl cation; catalytic hydrogenation yields the corresponding 1-arylalkanes.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 0300-922X
Last Modified: 04 Jun 2017 02:51
URI: http://orca.cf.ac.uk/id/eprint/12687

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