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A convenient procedure for bismuth-mediated Barbier-type allylation of aldehydes in water containing fluoride ions

Smith, Keith, Lock, Sandra, El-Hiti, Gamal A., Wada, Makoto and Miyoshi, Norikazu 2004. A convenient procedure for bismuth-mediated Barbier-type allylation of aldehydes in water containing fluoride ions. Organic & Biomolecular Chemistry 2 (6) , pp. 935-938. 10.1039/B400179F

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Abstract

A new and convenient procedure for synthesis of homoallylic alcohols in generally good to excellent yields has been developed. The bismuth-mediated Barbier-type allylation of aldehydes (aromatic, aliphatic, alicyclic and heterocyclic) with allyl bromide has been carried out smoothly in water in the presence of fluoride ions.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1477-0520
Date of First Compliant Deposit: 30 March 2016
Last Modified: 04 Jun 2017 02:51
URI: http://orca.cf.ac.uk/id/eprint/12707

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