Cardiff University | Prifysgol Caerdydd ORCA
Online Research @ Cardiff 
WelshClear Cookie - decide language by browser settings

Structural chemistry of a new chiral anhydrous phase of Ru(bipy)3(ClO4)2 established from powder x-ray diffraction analysis

Cheung, Eugene Y., Fujii, Kotaro, Guo, Fang, Harris, Kenneth David Maclean, Hasebe, Sayoko and Kuroda, Reiko 2011. Structural chemistry of a new chiral anhydrous phase of Ru(bipy)3(ClO4)2 established from powder x-ray diffraction analysis. Crystal Growth and Design 11 (8) , pp. 3313-3317. 10.1021/cg200379h

Full text not available from this repository.

Abstract

A new anhydrous chiral phase of Ru(bipy)3(ClO4)2 (bipy = 2,2′-bipyridine) has been prepared both by mechanical grinding followed by annealing of the known chiral hydrate phase of this material and by solid-state dehydration of the chiral hydrate phase at high temperature. The new phase is obtained from these processes as a microcrystalline powder, thus limiting the opportunity to carry out structural characterization by single-crystal X-ray diffraction. Instead, our structure determination of the new chiral anhydrous phase has exploited the capabilities of modern powder X-ray diffraction techniques, employing the direct-space genetic algorithm technique for structure solution followed by Rietveld refinement. The structural properties of the chiral anhydrous phase are discussed, particularly with regard to assessing the structural relationship to the parent hydrate phase.

Item Type: Article
Status: Published
Schools: Advanced Research Computing @ Cardiff (ARCCA)
Chemistry
Subjects: Q Science > QD Chemistry
Publisher: American Chemical Society
ISSN: 1528-7483
Last Modified: 04 Jun 2017 02:51
URI: http://orca.cf.ac.uk/id/eprint/12831

Citation Data

Cited 7 times in Google Scholar. View in Google Scholar

Cited 18 times in Scopus. View in Scopus. Powered By Scopus® Data

Actions (repository staff only)

Edit Item Edit Item