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Can gold be an effective catalyst for the Deacon reaction?

Malta, Grazia, Dawson, Simon R., Pattisson, Samuel, Edwards, Miles M., Freakley, Simon J., Dummer, Nicholas F., Schwab, Ekkehard, Bender, Michael, Teles, J. Henrique and Hutchings, Graham J. 2020. Can gold be an effective catalyst for the Deacon reaction? Catalysis Letters 150 , pp. 2991-2995. 10.1007/s10562-020-03204-0

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Abstract

The Deacon reaction is an important industrial process for the oxidation of hydrogen chloride, thereby enabling chlorine to be recycled. As gold is an efficient catalyst for reactions involving hydrogen chloride and oxygen, we have studied the use of gold as a potential catalyst for the Deacon reaction. Unfortunately, gold displays only limited activity; however, this is markedly increased if hydrogen is cofed as a reactant.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Publisher: Springer Verlag (Germany)
ISSN: 1011-372X
Funders: BASF
Date of First Compliant Deposit: 14 April 2020
Date of Acceptance: 27 March 2020
Last Modified: 16 Oct 2020 01:46
URI: http://orca.cf.ac.uk/id/eprint/130982

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