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A rhenium(I) complex which reacts with aldehydes and ketones in aqueous media: a structural, spectroscopic and theoretical analysis

Harding, Lindsay P., McRobbie, Asuka A. T., Riis-Johannessen, T., Pope, Simon J. A., Rice, Craig R., Rollinson, Donna and Whitehead, Martina 2020. A rhenium(I) complex which reacts with aldehydes and ketones in aqueous media: a structural, spectroscopic and theoretical analysis. JOURNAL OF CHEMICAL RESEARCH 10.1177/1747519820917888

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Abstract

A Re(I) complex of 3,3′-diamino-2,2′-bipyridine reacts irreversibly with aldehydes and unhindered ketones in water to form bis-aminal cyclised derivatives with the solid-state structure of the reaction with benzaldehyde reported. This reaction produces a Re(I) complex which is significantly more emissive than the starting compound.

Item Type: Article
Date Type: Published Online
Status: In Press
Schools: Chemistry
Publisher: SCIENCE REVIEWS 2000 LTD
ISSN: 1747-5198
Date of First Compliant Deposit: 15 June 2020
Date of Acceptance: 19 May 2020
Last Modified: 16 Jun 2020 12:00
URI: http://orca.cf.ac.uk/id/eprint/132459

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