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Biocatalyst mediated regio- and stereo-selective hydroxylation and epoxidation of (Z)-α-santalol

Daramwar, Pankaj P., Srivastava, Prabhakar Lal, Kolet, Swati P. and Thulasiram, Hirekodathakallu V. 2014. Biocatalyst mediated regio- and stereo-selective hydroxylation and epoxidation of (Z)-α-santalol. Organic and Biomolecular Chemistry 12 (7) , pp. 1048-1051. 10.1039/c3ob42174k

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Abstract

Biocatalyst mediated regio- and stereo-selective hydroxylation and epoxidation on (Z)-α-santalol were achieved for the first time, using a fungal strain Mucor piriformis. Four novel metabolites were characterized as 10,11-cis-β-epoxy-α-santalol, 5α-hydroxy-(Z)-α-santalol, 10,11-dihydroxy-α-santalol and 5α-hydroxy-10,11-cis-β-epoxy-α-santalol. Using Amano PS lipase from Burkholderia cepacia, α- and β-isomers of 10,11-cis-epoxy-α-santalol were resolved efficiently.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1477-0520
Date of Acceptance: 23 December 2013
Last Modified: 15 Jul 2020 13:00
URI: http://orca.cf.ac.uk/id/eprint/133382

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