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Dual role for phenylalanine 178 during catalysis by aristolochene synthase

Forcat, Silvia and Allemann, Rudolf Konrad 2004. Dual role for phenylalanine 178 during catalysis by aristolochene synthase. Chemical Communications (18) , pp. 2094-2095. 10.1039/b407932a

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Abstract

A mutant of aristolochene synthase, in which Phe 178 was replaced by Val, produced significant amounts of α- and β-farnesene as well as α and β-selinene and selina-4,11-diene, suggesting that Phe 178 is involved in the stabilisation of transition states preceding germacrene A and following eudesmane cation.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 1359-7345
Last Modified: 04 Jun 2017 02:54
URI: http://orca.cf.ac.uk/id/eprint/13486

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Cited 18 times in Web of Science. View in Web of Science.

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