Ayan, Dasgupta, Richards, Emma and Melen, Rebecca
2021.
Frustrated radical pairs: insights from EPR spectroscopy.
Angewandte Chemie International Edition
60
(1)
, pp. 53-65.
10.1002/anie.202010633
Item availability restricted. |
![]() |
PDF
- Accepted Post-Print Version
Restricted to Repository staff only until 15 September 2021 due to copyright restrictions. Download (2MB) |
Abstract
Recent progress in frustrated Lewis pair (FLP) chemistry has revealed the importance of the main group elements which has opened new avenues in synthetic chemistry. Recently, new reactivities of frustrated Lewis pairs have been uncovered that disclose certain combinations of Lewis acid and Lewis base undergo single electron transfer (SET) processes. Here a single electron can be transferred from the Lewis basic donor to a Lewis acid acceptor to produce a reactive frustrated radical pair (FRP). This review aims to highlight the recent advancements in this emerging field covering the synthesis and reactivities of frustrated radical pairs, with extensive highlights of Electron Paramagnetic Resonance (EPR) data to explain the nature and stability of the radical species.
Item Type: | Article |
---|---|
Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Publisher: | Wiley |
ISSN: | 1433-7851 |
Date of First Compliant Deposit: | 25 September 2020 |
Date of Acceptance: | 15 September 2020 |
Last Modified: | 06 Jan 2021 13:59 |
URI: | http://orca.cf.ac.uk/id/eprint/135090 |
Actions (repository staff only)
![]() |
Edit Item |