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Enhanced H2 uptake in solvents confined in mesoporous metal-organic framework

Clauzier, Stephanie, Ho, Linh Ngoc, Pera-Titus, Marc, Coasne, Benoit and Farrusseng, David 2012. Enhanced H2 uptake in solvents confined in mesoporous metal-organic framework. Journal of the American Chemical Society 134 (42) , pp. 17369-17371. 10.1021/ja308157a

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Abstract

Hydrogen uptake at 298 K and 30 bar in hybrid sorbents consisting of n-hexane confined in MIL-101 is found to be 22 times larger than in sole n-hexane. The enhanced solubility in MIL-101, found to be 3 times larger than in mesoporous silica of similar pore size, highlights the key roles played by surface chemistry and accessible surface area.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Publisher: American Chemical Society
ISSN: 0002-7863
Last Modified: 11 Jan 2021 15:30
URI: http://orca.cf.ac.uk/id/eprint/137413

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