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Enhancement of aldehyde-water shift reaction over CuZnAl catalyst by Mn promoter

Ye, Tongqi, Ai, Yue, Chen, Bao, Ye, Yuewen, Sun, Jia, Qin, Ling and Yao, Xin 2021. Enhancement of aldehyde-water shift reaction over CuZnAl catalyst by Mn promoter. Catalysis Communications 149 , 106262. 10.1016/j.catcom.2020.106262

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Abstract

A series of Mn promoted CuZnAl catalysts were prepared by coprecipitation method. Doping of manganese in CuZnAl strongly enhanced the AWS activity and propionic acid selectivity. The interaction between Cu and Mn ions results in suppressed the hydrogenation of propanal to propyl alcohol and enhanced the selectivity of propionic acid. According to our results, the most favorable Mn/Cu molar ratio is 1:1. Higher temperature is also beneficial to the selectivity of propionic acid on CuZnAl-based catalysts.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Additional Information: This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
Publisher: Elsevier
ISSN: 1566-7367
Date of First Compliant Deposit: 15 January 2021
Date of Acceptance: 27 November 2020
Last Modified: 19 Jan 2021 10:00
URI: http://orca.cf.ac.uk/id/eprint/137688

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