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A novel bipyridine-based hexadentate tripodal framework with a strong preference for trigonal prismatic co-ordination geometries

Knight, James Christopher, Alvarez, Santiago, Amoroso, Angelo James, Edwards, Peter Gerald and Singh, Neha 2010. A novel bipyridine-based hexadentate tripodal framework with a strong preference for trigonal prismatic co-ordination geometries. Dalton Transactions 39 (16) , pp. 3870-3883. 10.1039/b924651g

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Abstract

The synthesis of the novel ligand tris(2,2′-bipyrid-6-yl) methanol (L1) is described. Co-ordination of the ligand to the first row transition metals (Mn2+–Zn2+) as well as Cd2+ showed that the ligand formed complexes close to trigonal prismatic in geometry in the solid state. Analysis of the geometry of the co-ordination spheres showed varying degrees of trigonal prismatic and octahedral character. For each d-electron configuration, this could be related to the relative differences in ligand field stabilisation energies for the two geometries.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC
ISSN: 1477-9226
Last Modified: 04 Jun 2017 02:55
URI: http://orca.cf.ac.uk/id/eprint/13801

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