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Transition-metal-catalyzed reactions involving imidazolium salt/N-heterocyclic carbene couples as substrates

Clement, Nicolas David and Cavell, Kingsley John 2004. Transition-metal-catalyzed reactions involving imidazolium salt/N-heterocyclic carbene couples as substrates. Angewandte Chemie 43 (29) , pp. 3845-3847. 10.1002/anie.200454166

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Abstract

Reactive Couples: Imidazolium salts react with alkenes under mild conditions in the presence of a Ni0-based catalyst to produce 2-alkyl imidazolium salts (see scheme, cod=1,5-cyclooctadiene). The mechanism involves oxidative addition of an imidazolium CH bond to M0 to give a (carbene)MH intermediate and finally bond formation between the carbene and an alkyl ligand through reductive elimination.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Cardiff Catalysis Institute (CCI)
Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Wiley
ISSN: 1433-7851
Last Modified: 10 Oct 2017 12:42
URI: http://orca.cf.ac.uk/id/eprint/1389

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