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On the spontaneous induction of chirality in the preparation of Werner's complex cis-[CoBr(NH3)(en)2]Br2

Guo, Fang, Casadesus, Meritxell, Cheung, Eugene, Coogan, Michael Peter and Harris, Kenneth David Maclean 2006. On the spontaneous induction of chirality in the preparation of Werner's complex cis-[CoBr(NH3)(en)2]Br2. Chemical Communications (17) , pp. 1854-1856. 10.1039/b601530a

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Abstract

The product obtained directly from the standard reaction to produce Werner’s complex cis-[CoBr(NH3)(en)2]Br2 is shown, via structure determination from powder X-ray diffraction data, to be a racemic crystalline phase; implications of this observation in relation to previous reports that this reaction leads to significant enantiomeric excesses are discussed.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 1359-7345
Last Modified: 04 Jun 2017 01:39
URI: http://orca.cf.ac.uk/id/eprint/1397

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