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Novel synthesis of the monochloroborane–dimethyl sulphide complex via the reaction of borane–dimethyl sulphide with tetrachloromethane

Paget, Walter E. and Smith, Keith 1980. Novel synthesis of the monochloroborane–dimethyl sulphide complex via the reaction of borane–dimethyl sulphide with tetrachloromethane. Journal of the Chemical Society. Chemical communications (23) , pp. 1169-1170. 10.1039/C39800001169

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Abstract

Monochloroborane–dimethyl sulphide, BH2Cl.SMe2, is formed in essentially quantitative yield upon reflux of an equimolar mixture of borane–dimethyl sulphide, BH3.SMe2, and tetrachloromethane; it can be used directly for production of dialkylchloroboranes by the hydroboration of alkenes.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 0022-4936
Last Modified: 04 Jun 2017 02:57
URI: http://orca.cf.ac.uk/id/eprint/14512

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