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Highly para-selective mono-chlorination of aromatic compounds under mild conditions by t-Butyl hypochlorite in the presence of zeolites

Smith, Keith, Butters, Michael and Nay, Barry 1985. Highly para-selective mono-chlorination of aromatic compounds under mild conditions by t-Butyl hypochlorite in the presence of zeolites. Synthesis (Stuttgart) (12) , pp. 1157-1158. 10.1055/s-1985-31462

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Abstract

t-Butyl hypochlorite supported on H+, Na+ faujasite X (zeolite X) produces para-selective monchlorination of alkyl-, phenyl-, and halobenzenes under mild conditions; for example, chlorobenzene in acetonitrile (at 40°C) is chlorinated in high yield of isolated product (92%) to give dichlorobenzene with an isomer ratio 97% para/3% ortho.

Item Type: Article
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Georg Thieme Verlag
ISSN: 0039-7881
Last Modified: 04 Jun 2017 02:57
URI: http://orca.cf.ac.uk/id/eprint/14534

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