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Specific adsorption of barbituric acid on ferric(III) and nickel(II) oxides

Dmitrieva, I. B., Prokopovich, Polina, Tikhomolova, K. P. and Starov, V. M. 2004. Specific adsorption of barbituric acid on ferric(III) and nickel(II) oxides. Colloids and Surfaces A: Physicochemical and Engineering Aspects 239 (1-3) , pp. 19-24. 10.1016/j.colsurfa.2003.12.033

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Abstract

The dependence of NiO and Fe2O3 ζ-potential was investigated in the barbituric acid solutions (10−4 mol/l) as a function of pH by microelectrophoresis method. Shifting of pHIEP (the isoelectric point or IER) towards the acid zone for NiO and Fe2O3 in the solutions of barbituric acid (BA) in comparison with HCl shows the presence of the specific adsorption of the anion forms of BA. The complexation process of Ni(II) and Fe(III) ions with BA in the solution and on the surface of their oxides was examined by methods of conductometry and spectrophotometry. It was determined that nickel (II) and ferric (III) ions form complexes with BA both in solution and on the surface of their oxides.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Engineering
Pharmacy
Subjects: R Medicine > RM Therapeutics. Pharmacology
R Medicine > RS Pharmacy and materia medica
Uncontrolled Keywords: Nickel (II) oxide; Ferric (III) oxide; Barbituric acid; Microelectrophoresis; Specific adsorption; Surface complexation
Additional Information: Paper presented at XVIth European Chemistry at Interfaces Conference, 14-18 May, 2003, Vladimir, Russia
Publisher: Elsevier
ISSN: 0927-7757
Last Modified: 10 Nov 2017 13:53
URI: http://orca.cf.ac.uk/id/eprint/14685

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