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Structural origin of the gradual spin transition in a mononuclear iron(II) complex

Shepherd, Helena J., Rosa, Patrick, Fallis, Ian Andrew, Guionneau, Philippe, Howard, Judith A.K. and Goeta, Andrés E. 2012. Structural origin of the gradual spin transition in a mononuclear iron(II) complex. Journal of Physics and Chemistry of Solids 73 (2) , pp. 193-197. 10.1016/j.jpcs.2011.11.003

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Abstract

Variable temperature single crystal X-ray diffraction and SQUID magnetometry experiments have revealed a gradual spin transition in [FeII(L)](ClO4)2 (where L=1,4,7-tris(2-aminophenyl)-1,4,7-triazacyclononane), centred around room temperature. The gradual nature of the spin transition has been attributed to the lack of significant intermolecular interactions between iron centres and the propensity of the counter ions to accommodate the internal strain in the crystal caused by spin crossover.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Uncontrolled Keywords: A. Organometallic compounds; C. X-ray diffraction; D. Magnetic properties; * D. Crystal structure
Publisher: Elsevier
ISSN: 0022-3697
Last Modified: 04 Jun 2017 03:10
URI: http://orca.cf.ac.uk/id/eprint/17667

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