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Ion-tagged pi-acidic alkene ligands promote Pd-catalysed allyl-aryl couplings in an ionic liquid

Bäuerlein, Patrick S., Fairlamb, Ian J. S., Jarvis, Amanda G., Lee, Adam Fraser, Müller, Christian, Slattery, John M., Thatcher, Robert J., Vogt, Dieter and Whitwood, Adrian C. 2009. Ion-tagged pi-acidic alkene ligands promote Pd-catalysed allyl-aryl couplings in an ionic liquid. Chemical Communications (38) , pp. 5734-5736. 10.1039/b906823f

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Abstract

Ionic π-acidic alkene ligands based on chalcone and benzylidene acetone frameworks have been “doped” into ionic liquids to provide functional reaction media for Pd-catalysed cross-couplings of a cyclohexenyl carbonate with aryl siloxanes that allow simple product isolation, free from Pd (<50 ppm) and ligand contamination.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Cardiff Catalysis Institute (CCI)
Subjects: Q Science > QD Chemistry
Publisher: Royal Society of Chemistry
ISSN: 1359-7345
Last Modified: 19 Mar 2016 22:41
URI: http://orca.cf.ac.uk/id/eprint/23850

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