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EPR spectroscopy in catalysis

Van Doorslaer, Sabine and Murphy, Damien Martin 2012. EPR spectroscopy in catalysis. In: Drescher, Malte, Jeschke, Gunnar and Bordignon, E. eds. EPR Spectroscopy: Applications in Chemistry and Biology, Topics in Current Chemistry, vol. 321. Berlin: Springer, pp. 1-39. (10.1007/978-3-642-28347-5)

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Abstract

The modern chemical industry relies heavily on homogeneous and heterogeneous catalysts. Understanding the operational mode, or reactivity, of these catalysts is crucial for improved developments and enhanced performance. As a result, various spectroscopic techniques are inevitably used to characterize and interrogate the mechanistic details of the catalytic cycle. Where paramagnetic centres are involved, ranging from transition metal ions to defects and radicals, EPR spectroscopy is without doubt the technique of choice. In this review we will demonstrate the wealth and breadth of information that can be gleaned from this technique, in the characterization of homogenous and heterogeneous systems of catalytic importance, whilst illustrating the advantages that modern high-field and pulsed EPR methodologies can offer.

Item Type: Book Section
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Springer
ISBN: 9783642283468
Related URLs:
Last Modified: 04 Jun 2017 03:49
URI: http://orca.cf.ac.uk/id/eprint/27329

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