Hammond, Ceri, Forde, Michael M., Ab Rahim, Mohd Hasbi, Thetford, Adam, He, Qian, Jenkins, Robert Leyshon, Dimitratos, Nikolaos, Lopez-Sanchez, Jose Antonio, Dummer, Nicholas, Murphy, Damien Martin, Carley, Albert Frederick, Taylor, Stuart Hamilton, Willock, David James, Stangland, Eric E., Kang, Joo, Hagen, Henk, Kiely, Christopher John and Hutchings, Graham John 2012. Direct catalytic conversion of methane to methanol in an aqueous medium by using copper-promoted Fe-ZSM-5. Angewandte Chemie - International Edition 51 (21) , pp. 5129-5133. 10.1002/anie.201108706 |
Official URL: http://dx.doi.org/10.1002/anie.201108706
Abstract
Iron copper zeolite (Fe-Cu-ZSM-5) with aqueous hydrogen peroxide is active for the selective oxidation of methane to methanol. Iron is involved in the activation of the carbon–hydrogen bond, while copper allows methanol to form as the major product. The catalyst is stable, re-usable and activates methane giving >90 % methanol selectivity and 10 % conversion in a closed catalytic cycle (see scheme).
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Advanced Research Computing @ Cardiff (ARCCA) Chemistry Cardiff Catalysis Institute (CCI) |
Subjects: | Q Science > QD Chemistry |
Uncontrolled Keywords: | Copper; Heterogeneous catalysts; Iron; Methane; Zeolite |
Publisher: | Wiley-Blackwell |
ISSN: | 1433-7851 |
Last Modified: | 11 Feb 2021 02:26 |
URI: | http://orca.cf.ac.uk/id/eprint/30288 |
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