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Calcium amido-bisoxazoline complexes in asymmetric hydroamination/cyclisation catalysis

Nixon, Tracy D. and Ward, Benjamin David 2012. Calcium amido-bisoxazoline complexes in asymmetric hydroamination/cyclisation catalysis. Chemical Communications 48 (96) , pp. 11790-11792. 10.1039/c2cc37021b

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Abstract

Calcium complexes bearing bis(oxazolinylphenyl)amine (BOPA) ligands have been prepared, and their redistribution chemistry studied. The complexes [Ca(R-BOPA){N(SiMe3)2}(THF)] (R = iPr 1a, Ph 1b and Bn 1c) are active in hydroamination catalysis and give the highest enantioselectivity reported for a calcium complex.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: RSC Publishing
ISSN: 1359-7345
Date of First Compliant Deposit: 30 March 2016
Last Modified: 04 Jun 2017 04:29
URI: http://orca.cf.ac.uk/id/eprint/40013

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