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Supramolecular architectures of symmetrical dicationic ionic liquid based systems

Tadesse, Haregewine, Blake, Alexander J., Champness, Neil R., Warren, John E., Rizkallah, Pierre and Licence, Peter 2012. Supramolecular architectures of symmetrical dicationic ionic liquid based systems. Crystengcomm 14 (15) , pp. 4886-4893. 10.1039/c2ce25106j

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Abstract

Here we report the crystal structures of dicationic ionic liquids (ILs) with both modified cation and anion moieties and discuss the influence of the “supramolecular ionic liquid architecture” that these subtle changes incur. The four dicationic ILs, 1,8-bis(1-methylimidazolium-3-yl)octane bromide (1), 1,8-bis(1,2-dimethylimidazolium-3-yl)octane bromide (2), 1,8-bis(1,2-dimethylimidazolium-3-yl)octane tetrafluoroborate (3) and 1,12-bis(1-methylimidazolium-3-yl)dodecane bromide (4) were prepared using established literature methods. Single crystals of the materials were grown (as solvates for 1·2H2O and 4·1.2(C7H8)) and the solid-state structural arrangements determined by single crystal X-ray diffraction.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Medicine
Subjects: Q Science > QD Chemistry
R Medicine > R Medicine (General)
Publisher: Royal Society of Chemistry
ISSN: 1466-8033
Last Modified: 04 Jun 2017 04:38
URI: http://orca.cf.ac.uk/id/eprint/41914

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