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Aryl azide photochemistry in defined protein environments

Morris, Josephine Lydia, Reddington, Samuel C., Murphy, Damien Martin, Jones, Darran Dafydd, Platts, James Alexis and Tippmann, Eric Michael 2013. Aryl azide photochemistry in defined protein environments. Organic Letters 15 (4) , pp. 728-731. 10.1021/ol3028779

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Abstract

A genetically encoded precursor to an aryl nitrene, para-azidophenylalanine, was introduced site specifically into proteins to deduce if distinct environments were capable of caging a reactive organic intermediate. Following photolysis of mutant T4 lysozyme or green fluorescent proteins, EPR spectra showed, respectively, the presence of a triplet nitrene and an anilino radical.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Biosciences
Chemistry
Subjects: Q Science > QD Chemistry
Publisher: ACS
ISSN: 1523-7060
Funders: EPSRC
Last Modified: 12 Sep 2019 21:13
URI: http://orca.cf.ac.uk/id/eprint/45499

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