Meejoo, S., Kariuki, Benson ORCID: https://orcid.org/0000-0002-8658-3897 and Harris, Kenneth David Maclean ORCID: https://orcid.org/0000-0001-7855-8598 2003. The interplay of aryl-perfluoroaryl stacking interactions and interstack hydrogen bonding in controlling the structure of a molecular cocrystal. Chemphyschem 4 (7) , pp. 766-769. 10.1002/cphc.200300762 |
Official URL: http://dx.doi.org/10.1002/cphc.200300762
Abstract
Stacks of molecules: Structural properties of a 1:1 cocrystal formed between phenol and pentafluorophenol have been investigated by powder neutron diffraction. There are three crystallographically independent stacks which engage in interstack OH⋅⋅⋅O hydrogen bonds to form a hydrogen-bonded loop involving six OH groups (see picture). The H atom of each OH group is disordered between two positions, corresponding to two different hydrogen-bonding arrangements within the loop.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Chemistry |
Subjects: | Q Science > QC Physics |
Uncontrolled Keywords: | aryl-perfluoroaryl interactions;hydrogen bonding;powder neutron diffraction;stacking interactions |
Publisher: | Wiley-Blackwell |
ISSN: | 1439-4235 |
Last Modified: | 24 Oct 2022 11:10 |
URI: | https://orca.cardiff.ac.uk/id/eprint/47202 |
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