Acerbi, N., Edman Tsang, S. C., Jones, G., Golunski, Stanislaw E. and Collier, P. 2013. Rationalization of interactions in precious metal/ceria catalysts using the d-band center model. Angewandte Chemie - International Edition 52 (30) , pp. 7737-7741. 10.1002/anie.201300130 |
Official URL: http://dx.doi.org/10.1002/anie.201300130
Abstract
A correlation between ceria reducibility and precious metal d-band center is reported for ceria-supported precious metal catalysts. The results could provide the missing link to fully explain the occurrence of strong metal–support interaction (SMSI) and hydrogen spillover in catalysts that consist of dispersed metals in contact with reducible metal oxides.
Item Type: | Article |
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Date Type: | Publication |
Status: | Published |
Schools: | Cardiff Catalysis Institute (CCI) Chemistry |
Subjects: | Q Science > QD Chemistry |
Uncontrolled Keywords: | ceria; d-band center; electronic effect; redox chemistry; supported catalysts |
Publisher: | Wiley-Blackwell |
ISSN: | 1433-7851 |
Last Modified: | 08 Jan 2020 03:45 |
URI: | http://orca.cf.ac.uk/id/eprint/48198 |
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