Mechanism of electropolymerization of phenylacetylene in propylene carbonate

Garcia Canadas, Jorge, Lafuente, A., Rodriguez, G., Marcos, M. L. and Velasco, J. G. 2004. Mechanism of electropolymerization of phenylacetylene in propylene carbonate. Journal of Electroanalytical Chemistry 565 (1) , pp. 57-64. 10.1016/j.jelechem.2003.10.001

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Abstract

Electrooxidation of phenylacetylene (PAH) in a solution of 0.1 M in LiClO4 in propylene carbonate (PC) led to the formation of the conducting polymer poly(phenylacetylene) (PPA). A kinetic study has been made by experimental determination of the kinetic parameters. A mechanism is proposed which leads to confirmation of the experimental data. The electropolymerization product was isolated, purified, and characterized. Spectroscopic data showed that the polymer obtained consists in a linear polyene chain with a trans structure. The average molar mass determined was 3095, corresponding to the formation of a polymer with around 30 monomer units and to an electrical efficiency of 3095 g of polymer/mol of electrons.

Item Type:	Article
Date Type:	Publication
Status:	Published
Schools:	Engineering
Subjects:	T Technology > TA Engineering (General). Civil engineering (General)
Uncontrolled Keywords:	Polyphenylacetylene; Electropolymerization mechanism; Kinetic study
Additional Information:	Erratum at http://dx.doi.org/10.1016/j.jelechem.2004.04.001
Publisher:	Elsevier
ISSN:	1572-6657
Last Modified:	19 Mar 2016 23:21
URI:	https://orca.cardiff.ac.uk/id/eprint/48402

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