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An ENDOR study of oxomolybdenum(V) tris(pyrazolyl)borate complexes; identification of couplings to boron and other

Farley, Robert D., Hoefer, Peter, Maher, John P., McCleverty, JA, Murphy, Damien Martin, Rowlands, Christopher C., Ung, Van A. and Ward, Michael D. 2002. An ENDOR study of oxomolybdenum(V) tris(pyrazolyl)borate complexes; identification of couplings to boron and other. Magnetic Resonance in Chemistry 40 (11) , pp. 683-686. 10.1002/mrc.1090

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Abstract

11B hyperfine and quadrupolar couplings have been observed by the electron magnetic resonance techniques electron nuclear double resonance and hyperfine sublevel correlation spectroscopy for some tris(pyrazolyl)borato-oxomolybdenum(V) and related nitrosyl complexes including a dinuclear B–B linked complex. The spectra are interpreted according to the electron delocalization onto the ligands, especially the pyrazolylborate.

Item Type: Article
Date Type: Publication
Status: Published
Schools: Chemistry
Subjects: Q Science > QD Chemistry
Publisher: Wiley-Blackwell
ISSN: 0749-1581
Last Modified: 04 Jun 2017 05:06
URI: http://orca.cf.ac.uk/id/eprint/48503

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